fxcss pick
fxcss 0.22.1Source documentation
bash
fxcss pickThe answer to "what is this thing called?" Move the mouse over the browser window and the element under the cursor is outlined, with its selector shown in a label:

Click it and your terminal prints everything you need:
example
toolbarbutton → #back-button
classes toolbarbutton-1 chromeclass-toolbar-additional
box 32×36 at (88, 8)
styles
color: rgba(46, 52, 54, 0.35)
border-radius: 8px
list-style-image: url("chrome://browser/skin/back.svg")
styled by 11 rules in this theme
chrome/parts/buttons-fixes.css:5 :root:not([uidensity=compact]) #back-button {
chrome/parts/custom-icons.css:6 #nav-bar #back-button .toolbarbutton-icon {
chrome/parts/headerbar.css:76 #nav-bar #back-button:not(#hack) {That last section is the useful part: not just what the element is, but which of your files already style it, with line numbers. Keep clicking to pick more; Esc in the browser or Ctrl-C in the terminal stops.